Decay times of 4-(dimethylamino)benzonitrile in acetonitrile and conclusions on entropy of activation
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Decay times of 4-(dimethylamino)benzonitrile in acetonitrile and conclusions on entropy of activation
From picosecond decay times of 4-(dimethylamino)benzonitrile (DMABN) and 4-(dimethylamino)benzoic acid ethyl ester (DMABE) in acetonitrile (Ref. [1]), a conclusion on entropy effects cannot be made because of large uncertainties of the data. The planarized 1-tert-butyl-6-cyano-1,2,3,4-tetrahydroquinoline (NTC6) as a model for a planar intramolecular charge transfer (ICT) state and the influence...
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ژورنال
عنوان ژورنال: Chemical Physics Letters
سال: 2009
ISSN: 0009-2614
DOI: 10.1016/j.cplett.2009.10.094